Glass transition, melting point, deflection temperature under load, and maximum continuous and intermittent service temperature for thirteen engineering plastics, ordered by continuous rating.
Data verified 2026-09-29 · based on n/a — UL does not year-stamp 746B; RTI values as published for each grade
| Material[1] | Glass transition °C[1] | Melting point °C[1] | Deflection temp @ 1.8 MPa °C[1] | Max continuous °C[2] | Max intermittent °C[2] | Note[1] |
|---|---|---|---|---|---|---|
| Rigid PVC # | 80 | none (amorphous) | 70 | 60 | 80 | Softens gradually; not a structural material when hot |
| Acrylic (PMMA) # | 105 | none (amorphous) | 82 | 65 | 90 | Tg governs; there is no crystalline phase |
| UHMW-PE # | −120 | 135 | 80 | 80 | 100 | Lowest ceiling of the common engineering plastics |
| POM-H (Delrin) # | −60 | 175 | 125 | 85 | 149 | DTUL is high relative to the continuous rating |
| POM-C (Acetal copolymer) # | −60 | 166 | 110 | 100 | 140 | Slightly lower melting point than POM-H |
| Nylon 6/6 # | 50 | 265 | 75 | 105 | 150 | DTUL at 1.8 MPa is only 75 °C despite the 265 °C melt |
| Polycarbonate # | 147 | none (amorphous) | 132 | 115 | 130 | Tough and transparent; not for hot water |
| PET-P (Ertalyte) # | 75 | 255 | 80 | 120 | 150 | Better wear than acetal at higher temperature |
| PEI (Ultem) # | 217 | none (amorphous) | 200 | 170 | 200 | Inherently UL94 V-0, no additives |
| PES (Polyethersulfone) # | 225 | none (amorphous) | 203 | 180 | 200 | Amorphous; transparent and steam-sterilisable |
| PPS # | 90 | 280 | 110 | 220 | 240 | High ceiling but brittle; DTUL at load is far below the melt |
| PEEK # | 143 | 343 | 152 | 250 | 300 | The highest continuous rating of the melt-processable plastics |
| PTFE # | −97 | 327 | 55 | 260 | 290 | Highest melting point here, lowest DTUL under load |
Continuous ratings follow the UL 746B relative thermal index where one is published, and supplier data-sheet ratings otherwise. The melting point column is not a service limit — it is the temperature at which the crystalline phase disappears under zero load. A part carrying load fails far below it, which is what the deflection temperature column measures. Amorphous plastics (PVC, acrylic, polycarbonate, PEI, PES) have no melting point at all; they soften progressively above their glass transition.
Four different temperatures appear in this table, and using the wrong one is the most common material selection error:
Glass transition temperature (Tg) is where an amorphous plastic changes from glassy and stiff to rubbery and compliant. For an amorphous plastic — PVC, acrylic, polycarbonate, PEI, PES — this is the real ceiling, because stiffness falls off a cliff above it. For a semi-crystalline plastic it matters much less, because the crystalline regions keep the material stiff well past Tg. That is why nylon 6/6 has a Tg of only 50 °C yet works at 105 °C.
Melting point is the temperature at which the crystalline phase disappears. It is a materials-science number, not a design limit. A part held near its melting point has essentially no stiffness regardless of what the data sheet's room-temperature tensile strength says.
Deflection temperature under load (DTUL) is the useful one. It measures the temperature at which a standard specimen deflects a fixed amount while carrying a specified load — 1.8 MPa (264 psi) in the column above, or 0.46 MPa (66 psi) in the lighter test. It directly answers "at what temperature will my part start to sag under its own load?" Note PTFE: a melting point of 327 °C, the second highest here, but a DTUL of only 55 °C. The high melting point is irrelevant to a loaded part.
Maximum continuous service temperature is a long-term property, usually taken from the UL relative thermal index. It reflects how long the material retains half its original property value at that temperature — a measure of thermal ageing, not of instantaneous strength. It is typically higher than the DTUL, because a part can survive at a temperature where it would deflect if loaded.
The table splits naturally into two groups, and the split predicts most of the differences in behaviour you will notice in the shop.
Semi-crystalline plastics — POM, nylon, PEEK, PPS, PET, UHMW-PE, PTFE — have ordered regions that hold the material stiff up to near the melting point. They are opaque or translucent, resist fatigue and wear well, do not stress-crack readily, and hold strength above Tg. They shrink noticeably on cooling from the melt and their machined surfaces can be slightly waxy or crystalline in appearance.
Amorphous plastics — PVC, acrylic, polycarbonate, PEI, PES, PSU — have randomly arranged chains with no crystalline order. They are usually transparent, shrink less and more predictably, machine to a glassier finish, and are stiffer at room temperature. Their weakness is that once past Tg their stiffness collapses rather than declining gradually, and many of them stress-crack in contact with solvents.
This is why the four amorphous materials in the table cluster in the middle: they are excellent at room temperature and unusable near their Tg. It is also why PEEK and PTFE sit at the top — both are semi-crystalline with very high melting points.
Each data column on this page is tied to the source it came from. The numbers in square brackets correspond to the table headers above.
| # | Source | Type | Revision / method |
|---|---|---|---|
| [1] | Published unfilled-grade property data sheets (thermal section) | standard | supplier data sheets as published 2024–2026 |
| [2] | UL 746B — Polymeric Materials, Long Term Property Evaluations | standard | n/a — UL does not year-stamp 746B; relative thermal index as published for the grade |
| Standard | Revision | What it covers on this page |
|---|---|---|
| UL 746B — Polymeric Materials, Long Term Property Evaluations | n/a — UL does not year-stamp 746B; RTI values as published for each grade | the maximum continuous service temperature column |
| ASTM D648 — Deflection Temperature of Plastics Under Flexural Load | ASTM D648-18 | the deflection temperature under load column |
| ASTM D3418 / D789 / D4591 — transition and melting temperatures | ASTM D3418-21, D789-19, D4591-17 | the glass transition and melting point columns |
Cross-checked against:
Values are for unfilled, natural-grade resin. Glass- and mineral-filled grades raise the deflection temperature substantially — a 30% glass-filled nylon 6/6 deflects at 250 °C where the unfilled grade deflects at 75 °C — so a filled grade's data sheet is required for any elevated-temperature design. Continuous ratings describe thermal ageing, not instantaneous strength: a part at its continuous rating may still be far too hot to carry load.
Every value on this page is traceable to the sources listed above. If you use the data in a document, paper or report, cite it as:
Each row in the tables above also has a permanent link — hover a row and use the # link to cite a single value rather than the whole page.
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